[(S,S)-Teth-TsDpen RuCl]

CAS NO:851051-43-9
包装规格:100 MG,500 MG,100mg,500mg
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产品价格
产品编号品牌包装单位单价(元)现货
3338114Sigma-Aldrich100 MG1050请咨询
3338114Sigma-Aldrich500 MG2830请咨询
3554830Strem100mg1500请咨询
3554830Strem500mg3310请咨询
结构式
基本信息
Empirical Formula【经验(实验)分子式】
C30H31ClN2O2RuS
Molecular weight
620.17
PubChem Substance ID【PubChem化学物质编号】
329766311
NACRES
NA.22
Application【应用】
[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:
  • In the reduction of a ketone intermediate for the synthesis of esketamine.
  • In asymmetric hydrogenation of acetylenic ketones.
  • For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.

产品性质
optical activity【旋光性】
[α]22/D +339°, c = 0.5% in chloroform
Quality Level【质量水平】
100
reaction suitability
core: ruthenium
reagent type: catalyst
mp
260-268 ℃
storage temp.【储存温度】
2-8℃
SMILES string
Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5
InChI
1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1
InChI key
MDABGVLQRDDWLY-ARDORAJISA-M
packaging【包装】
100 mg in clear glass bottle
500 mg in amber glass bottle
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
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