3-甲基-2-氧化吲哚

3-Methyl-2-oxindole
CAS NO:1504-06-9
规格:96%
包装规格:5 G,25 G,250mg,1g,5g,10g,25g
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产品价格
产品编号品牌包装单位单价(元)现货
3298561Sigma-Aldrich5 G750请咨询
3298561Sigma-Aldrich25 G2960请咨询
4041268Alfa Aesar250mg216请咨询
4041268Alfa Aesar1g452请咨询
4041268Alfa Aesar5g1200请咨询
4041268Alfa Aesar10g1900请咨询
4041268Alfa Aesar25g3830请咨询
结构式
基本信息
Empirical Formula【经验(实验)分子式】
C9H9NO
Molecular weight
147.17
MDL number
MFCD04037370
PubChem Substance ID【PubChem化学物质编号】
24872867
NACRES
NA.22
General description【一般描述】
3-Methyl-2-oxindole (MOI) is a 3-substituted-2-oxindole. It is reported to be formed during the oxidation of indole-3-acetic acid in the presence of FeII under aerobic conditions. MOI undergoes asymmetric anti-Mannich-type reaction with N-tosyl aryl aldimines in the presence of alkaloid cinchona derivatives to form anti-3,3-disubsituted 2-oxindole derivatives. It also undergoes asymmetric hydroxyamination with nitrosoarenes to form N-nitroso aldol products.
Application【应用】
3-Methyl-2-oxindole may be used in the preparation of 3-hydroxy-3-methyl-2-oxindole.
  • Reactant for enantioselective α-amination reactions
  • Reactant for aldol reaction with glyoxal derivatives
  • Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes
  • Reactant for O-acetylation reactions
  • Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions
产品性质
Quality Level【质量水平】
100
Assay【测定】
96%
mp
117-121 ℃ (lit.)
SMILES string
CC1C(=O)Nc2ccccc12
InChI
1S/C9H9NO/c1-6-7-4-2-3-5-8(7)10-9(6)11/h2-6H,1H3,(H,10,11)
InChI key
BBZCPUCZKLTAJQ-UHFFFAOYSA-N
packaging【包装】
5, 25 g in glass bottle
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type N95 (US)
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