产品价格
| 产品编号 | 品牌 | 包装单位 | 单价(元) | 现货 |
| 3034675 | Alfa Aesar | 1g | 1880 | 请咨询 |
| 3034675 | Alfa Aesar | 10g | 2240 | 请咨询 |
| 3034675 | Alfa Aesar | 50g | 6720 | 请咨询 |
| 3250069 | Sigma-Aldrich | 10 G | 1300 | 请咨询 |
| 3557481 | Strem | 2g | 486 | 请咨询 |
| 3557481 | Strem | 10g | 1350 | 请咨询 |
结构式
 |
基本信息
| 应用 | Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions. |
| 备注 | Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture. |
| MDL | MFCD00013615 |
| EINECS | 247-386-9 |
| 分子式 | C4H9Cl2P |
| 分子量 | 159.00 |
| 熔点 | 44-49° |
| 灵敏度 | Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures. |
| 形态 | Crystalline solid |
| 溶解性 | Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents. |
| 包装组 | II |
| 危险类别 | 14-34 Reacts violently with water.Causes burns. |
安全信息
| 危险等级 | 8 |
| 安全等级 | 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
| 欧盟危险品标志 |  |
| TSCA | 否 |
GHS危害和防范说明
| GHS符号 |  |
| Hazard Statements | H314-H318 Causes severe skin burns and eye damage.Causes serious eye damage. |
| Precautionary Statements | P280-P305+P351+P338-P309-P310-P402 Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.Store in a dry place. |