甲基异丁烯铜(I)
Mesitylcopper(I)
产品价格
| 产品编号 | 品牌 | 包装单位 | 单价(元) | 现货 |
| 3108929 | Sigma-Aldrich | 1 G | 2880 | 请咨询 |
| 3108929 | Sigma-Aldrich | 5 G | 9550 | 请咨询 |
| 3550835 | Strem | 1g | 2310 | 请咨询 |
| 3550835 | Strem | 5g | 8370 | 请咨询 |
结构式
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基本信息
| Empirical Formula【经验(实验)分子式】 | C9H11Cu |
| Molecular weight | 182.73 |
| MDL number | MFCD00015622 |
| PubChem Substance ID【PubChem化学物质编号】 | 329765125 |
| NACRES | NA.22 |
| General description【一般描述】 | Mesitylcopper(I) is a thermally stable and highly soluble organocopper compound, which is commonly used as a metalation reagent in organic synthesis. In mixed lithium cuprate reagents, mesitylcopper serves as a useful ″holding group″. It is very sensitive to moisture and air therefore reactions must be carried out under anhydrous conditions. |
| Application【应用】 | Mesitylcopper(I) is can be used to synthesize:
It can also be used as a selective mesityl group transfer reagent in stoichiometric C−C and C−heteroatom bond-forming reactions. |
产品性质
| reaction suitability | core: copper reagent type: catalyst |
| Quality Level【质量水平】 | 100 |
| mp | 184-191 ℃ |
| storage temp.【储存温度】 | 2-8℃ |
| SMILES string | Cc1cc(C)c([Cu])c(C)c1 |
| InChI | 1S/C9H11.Cu/c1-7-4-8(2)6-9(3)5-7;/h4-5H,1-3H3; |
| InChI key | BBUKMFLZOHNUQU-UHFFFAOYSA-N |
| packaging【包装】 | 1, 5 g in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |