1-(溴乙酰)芘

C₁₈H₁₁BrO

323.18

MFCD00191839

24864593

NA.22

1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

1-(Bromoacetyl)pyrene is suitable for use in the following studies:

• As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
• As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
• As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.

It may also be used in the following studies:

• As a photoremovable protecting group for carboxylic acids and amino acids.
• As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
• As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
• As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.

100

97%

129-131 ℃ (lit.)

BrCC(=O)c1ccc2ccc3cccc4ccc1c2c34

1S/C18H11BrO/c19-10-16(20)14-8-6-13-5-4-11-2-1-3-12-7-9-15(14)18(13)17(11)12/h1-9H,10H2

KAEDEGFCOPIKKM-UHFFFAOYSA-N

5 g in glass bottle

GHS05

Danger

H314 - H413

P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Aquatic Chronic 4 - Skin Corr. 1B

8A - Combustible, corrosive hazardous materials

WGK 3

Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges